Howdy Chags,
The PSHCP card along with her Provincial Health Care plan card is all that is required. As you add dependants onto your military records (make sure you add them!), they are automatically covered with PSHCP.
There is also the CF Dental Care plan, but you aren't issued a card for that. Simply go to your OR and they can provide you with claim forms and an explanation of benefits. Most dentists that are familiar with the CFDCP will submit the claim on your behalf and simply bill you the remaining portion, but that is their choice. They may prefer for you to pay up front and for you to submit the claim.
There is also a Blue Cross card that is available for your use, but it covers only you on lve while outside Canada. Basically, the card simply provides a contact number to arrange emergency medical and dental coverage while on lve outside the country, but again, I stress that it covers only you. If you are taking the family out of the country, I would recommend investing in supplementary Blue Cross or similar coverage.
Other than that, there are no other plans that I am aware of, however, it may vary from province to province. However, if you have any doubts, consult your OR staff. Better to ask and be informed than to be silent and miss out on benefits due to you. Cheers.